Preliminary Numerical Simulation of Methane Steam Reforming in Porous Catalytic Media
DOI:
https://doi.org/10.70567/mc.v42.ocsid8624Keywords:
Methane steam reforming, Hydrogen production, Porous media, Numerical simulation, Catalytic reactorAbstract
This work presents preliminary results of the numerical simulation of methane steam reforming in a porous catalytic medium, considering exclusively the global reaction with methane without the gas-shift reaction. The model was implemented in COMSOL Multiphysics based on the classical formulation of Darcy’s law, the energy balance in porous media, and the transport of concentrated species. The analyses were performed in a simplified cylindrical geometry, varying the reactor length, the inlet temperature (800 and 900 K), and the methane/water feed ratio. The results indicated that longer reactors and higher temperatures enhance methane conversion and hydrogen production, whereas the feed composition revealed trade-offs between relative conversion and absolute productivity. This study aligns with established trends in the literature and serves as the preliminary stage of an ongoing master’s research project. Future work will involve extensive parametric analysis, integration of multiple reaction pathways, and a detailed investigation of process selectivity.
References
Dincer I., and Acar C., Review and evaluation of hydrogen production methods for better sustainability. International Journal of Hydrogen Energy, 42:3471–3482, 2017. http://doi.org/10.1016/j.ijhydene.2016.06.043
Furlan J., Martins J. A., Romão E. C., Dispersion of toxic gases (CO and CO2) by 2D numerical simulation, Ain Shams Engineering Journal, Volume 10, Issue 1, 2019, Pages 151-159. https://doi.org/10.1016/j.asej.2018.03.010.
IEA – International Energy Agency, The Future of Hydrogen: Seizing today’s opportunities. Paris: IEA, 2019. https://www.iea.org/reports/the-future-of-hydrogen
JAEA (Japan Atomic Energy Agency), Thermodynamic data – NiO. 2025. Access in 09/03/2025. https://thermodb.jaea.go.jp/data/en/td/NiO.html
Johnson Matthey, Steam reforming catalysts. 2022. Access in 09/03/2025. https://matthey.com/documents/161599/348563/JM+Steam+reforming+catalysts+Product+Brochure.pdf/99deb020-f1af-f436-c6b3-a3557ad2499e?t=1664979352415
Neves, O. A., Romão, E. C., Campos-Silva, J. B. and Moura, L. F. M. (2011), Numeric simulation of pollutant dispersion by a control-volume based on finite element method. Int. J. Numer. Meth. Fluids, 66: 1073-1092. https://doi.org/10.1002/fld.2296
Shabani B., and Aghakhani A., Hydrogen as a fuel for transportation: Technology, infrastructure and perspectives. Renewable and Sustainable Energy Reviews, 134:110196, 2020. http://doi.org/10.1016/j.rser.2020.110196
Xu J., and Froment G.F., Mathematical modeling of monolithic catalysts for steam reforming of methane. AIChE Journal, 35:88–96, 1989. http://doi.org/10.1002/aic.690350109
Zeppieri M., Villa P.L., Verdone N., Scarsella M., and De Filippis P., Kinetic of methane steam reforming reaction over nickel- and rhodium-based catalysts. Applied Catalysis A: General, 387:147–154, 2010. http://doi.org/10.1016/j.apcata.2010.08.017
Zhao J., et al., Recent advances in hydrogen production: catalysis and process development. Chemical Engineering Journal, 421:129804, 2021. http://doi.org/10.1016/j.cej.2020.129804
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