Modelling the Thermal Energy Storage of Cementitious Mortars Made with PCM-Vermiculite Aggregates
DOI:
https://doi.org/10.70567/mc.v42.ocsid8579Palavras-chave:
Thermal Energy Storage, FEM simulation, phase-change materials-vermiculite aggregates, latent heat, enthalpy method, Stefan problemResumo
This paper presents a finite element modelling (FEM)-based approach to simulate the thermal performance and latent heat behavior of sustainable cementitious mortars incorporating Phase Change Material–Vermiculite Aggregates (PCM-VAs). These advanced composites are designed to enhance thermal energy storage capabilities within building materials using porous vermiculite as a carrier medium for bio-based PCMs. An enthalpy-porosity formulation was adopted to solve the Stefan problem within the framework of coupled transient heat transfer, allowing for phase-change phenomena to be accurately captured across multi-scale domains. The FEM model was calibrated and validated using experimental data from an in-house testing program focused on optimized PCM impregnation techniques for vermiculite. The simulation results demonstrated good agreement with experimental measurements, effectively capturing the temperature evolution and storage-release cycles. This work supports the potential of PCM-VAs as a functional aggregate for low-carbon thermal regulation in cement-based construction systems.
Referências
Abdolahimoghadam, M., & Rahimi, M. (2024). New hybrid nano- and bio-based phase change material containing graphene-copper particles hosting beeswax-coconut oil for solar thermal energy storage: Predictive modeling and evaluation using machine learning. Energy, 307, 132604. https://doi.org/10.1016/j.energy.2024.132604
Abdolahimoghadam, M., & Rahimi, M. (2025). Experimental, numerical, and machine learning study of vertical thermal energy storage filling with novel hybrid nano- and bio-based phase change material. Journal of Energy Storage, 106, 114815. https://doi.org/10.1016/j.est.2024.114815
Adesina, A. (2021). Overview of the influence of waste materials on the thermal conductivity of cementitious composites. Cleaner Engineering and Technology, 2, 100046. https://doi.org/10.1016/j.clet.2021.100046
Chin, C. O., & Sih, Y. K. (2018). Thermal Properties of Concrete Incorporated with Shape-stable Phase Change Material. MATEC Web of Conferences, 203, 06021. https://doi.org/10.1051/matecconf/201820306021
El Majd, A., Younsi, Z., Youssef, N., Belouaggadia, N., & El Bouari, A. (2023). Experimental study of thermal characteristics of bio-based textiles integrating microencapsulated phase change materials. Energy and Buildings, 297, 113465. https://doi.org/10.1016/j.enbuild.2023.113465
Haider, M. Z., Jin, X., & Hu, J. W. (2023). Development of nanomodified-cementitious composite using phase change material for energy saving applications. Applied Energy, 340, 121067. https://doi.org/10.1016/j.apenergy.2023.121067
Jin, X., Haider, M. Z., Ahn, J., Fang, G., & Hu, J. W. (2023). Development of nanomodified eco-friendly thermal energy storing cementitious composite using PCM microencapsulated in biosourced encapsulation shell. Case Studies in Construction Materials, 19, e02447. https://doi.org/10.1016/j.cscm.2023.e02447
Jin, X., Haider, M. Z., & Hu, J. W. (2024). Enhancing thermal energy storage efficiency at low temperatures with innovative macro-encapsulation of nano phase change material in cementitious composites. Construction and Building Materials, 449, 138187. https://doi.org/10.1016/j.conbuildmat.2024.138187
Krakowiak, K. J., Nannapaneni, R. G., Moshiri, A., Phatak, T., Stefaniuk, D., Sadowski, L., & Abdolhosseini Qomi, M. J. (2020). Engineering of high specific strength and low thermal conductivity cementitious composites with hollow glass microspheres for high-temperature high-pressure applications. Cement and Concrete Composites, 108, 103514. https://doi.org/10.1016/j.cemconcomp.2020.103514
Kumar, A., Somani, P., Sain, A., & Gaur, A. (2023). Enhancing thermal behaviour of concrete pavement by incorporating vermiculite. Materials Today: Proceedings, 93. https://doi.org/10.1016/j.matpr.2023.07.302
Liang, Q., Pan, D., & Zhang, X. (2023). Construction and application of biochar-based composite phase change materials. Chemical Engineering Journal, 453, 139441. https://doi.org/10.1016/j.cej.2022.139441
Liu, L., Fan, X., Zhang, Y., Zhang, S., Wang, W., Jin, X., & Tang, B. (2020). Novel bio-based phase change materials with high enthalpy for thermal energy storage. Applied Energy, 268, 114979. https://doi.org/10.1016/j.apenergy.2020.114979
Mankel, C., Caggiano, A., Koenig, A., Said Schicchi, D., Nazari Sam, M., & Koenders, E. (2020). Modelling the Thermal Energy Storage of Cementitious Mortars Made with PCM-Recycled Brick Aggregates. Materials, 13, 1064. https://doi.org/10.3390/ma13051064
Mo, K. H., Lee, H. J., Liu, M. Y. J., & Ling, T. C. (2018). Incorporation of expanded vermiculite lightweight aggregate in cement mortar. Construction and Building Materials, 179, 302–306. https://doi.org/10.1016/J.CONBUILDMAT.2018.05.219
Montazerian, A., Arve Øverli, J., & Goutianos, S. (2023). Thermal conductivity of cementitious composites reinforced with graphene-based materials: An integrated approach combining machine learning with computational micromechanics. Construction and Building Materials, 395, 132293. https://doi.org/10.1016/j.conbuildmat.2023.132293
Nazari, M., Jebrane, M., & Terziev, N. (2020). Bio-Based Phase Change Materials Incorporated in Lignocellulose Matrix for Energy Storage in Buildings—A Review. Energies, 13(12), 3065. https://doi.org/10.3390/en13123065
Neto, P., Sales, L., Oliveira, P., Silva, I., Barros, I., Nóbrega, A., & Carneiro, A. (2023). Expanded Vermiculite: A Short Review about Its Production, Characteristics, and Effects on the Properties of Lightweight Mortars. Buildings, 13, 823. https://doi.org/10.3390/buildings13030823
Sam, M. N., Caggiano, A., Mankel, C., & Koenders, E. (2020). A comparative study on the thermal energy storage performance of bio-based and paraffin-based PCMs using DSC procedures. Materials, 13(7). https://doi.org/10.3390/ma13071705
Schackow, A., Effting, C., Folgueras, M. V., Güths, S., & Mendes, G. A. (2014). Mechanical and thermal properties of lightweight concretes with vermiculite and EPS using air-entraining agent. Construction and Building Materials, 57, 190–197. https://doi.org/10.1016/J.CONBUILDMAT.2014.02.009
Siddesh, J. S., Shivaprasad, K. N., & Yang, H. M. (2025). Enhancing the thermal performance of cementitious composites: A comprehensive review of phase change material integration. Applied Thermal Engineering, 268, 125849. https://doi.org/10.1016/j.applthermaleng.2025.125849
Simpson, A., & Stuckes, A. D. (1987). Thermal conductivity of vermiculite concrete: Effect of inclusion shape. Building Services Engineering Research and Technology, 8(1), 1–4. https://doi.org/10.1177/014362448700800101
Vitola, L., Pundiene, I., Pranckeviciene, J., & Bajare, D. (2025). Innovative Hemp Shive-Based Bio-Composites, Part II: The Effect of the Phase Change Material (PCM) Additive on Characteristics of Modified Potato Starch Binders. Materials, 18(4), 891. https://doi.org/10.3390/ma18040891
Yang, Y., Wang, Y., & Cao, J. (2023). Prediction and evaluation of thermal conductivity in nanomaterial-reinforced cementitious composites. Cement and Concrete Research, 172, 107240. https://doi.org/10.1016/j.cemconres.2023.107240
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